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Ontario Fire Service Messenger

November/December 2004                Volume 13 Issue 4

Fire Behaviour and the Chemistry of Combustion

Teaching Plan
Practical Self-Check

Introduction:

Firefighters are bound by the technical and ethical standards of the profession. Possessing both theoretical and technical knowledge is an absolute must if you are going to be a true professional.

This session deals with fire behaviour, its classification, and the four basic methods of extinguishment.

Learning Outcomes:

The firefighter will:

a) define fire

b) explain the reasons for studying fire and its behaviour

c) explain the elements of the fire triangle and the fire tetrahedron and their relationship to one another: fuel - oxygen - heat - molecular chain reaction

d) define and describe the stages of fire

e) describe the types of fire

f) define the following terms relating to fire - phenomenon of BLEVE, flashover, backdraft, rollover, pyrolysis, flash point, fire point and ignition temperature

g) identify the four classes of fire and give two examples of fuels in each class

h) define the four methods of heat transfer

i) describe the methods of extinguishment

j) describe the five sources of heat energy

k) describe the effects of heat on solid, liquid and gaseous fuels

l) describe the nature of the products of combustion produced during a fire

m) describe the factors that influence the production of toxic gases

n) identify the most common combustion gases produced during a fire and describe their sources and effect on fire

o) describe the physical properties of each of the common combustion gases

p) describe the burning characteristics of the four classes of fire

q) describe common fire service extinguishing agents

r) describe the extinguishing agents appropriate to each class of fire along with the advantages and disadvantages of each

s) describe the ways different types of building construction affect fire behaviour

t) identify structural features which influence fire spread and safety

u) describe the influence of the following factors on total fire safety:

• how building construction affects fire behaviour

• how structural features influence fire spread and safety

Expectations of the Participant:

a) listen actively

b) participate in group discussions

c) ask questions for clarification and understanding

d) answer instructor questions

e) be a team player

 

Key Points and Terms

Student Learning Activity

References and Resources

Trainer/Facilitator Activity

Reasons for studying fire:

• firefighter safety
• methods of extinguishment
• methods of spread • methods of preventing
• effects on people, building materials & clothing
 
Read IFSTA, Chapter 2: Fire Behaviour
 
IFSTA Essentials of Fire Fighting, 4th Edition
 

• lead lesson

• record on flip chart

• answer questions

• involve learners

• emphasize the importance of knowing how fire burns and reacts
 

The Fire Tetrahedron

• heat
- sources
- amount
- intensity

• fuel
- matter
- solid
- liquid
- gas

• effects of heat on matter
- expansion
- fusion
- vaporization
- pyrolysis

• oxygen
- sources
- supports combustion

• chemical chain reaction
- molecular bonds

- free radicals
- oxidation react- ion
- exothermic
- self-sustaining
 

Read IFSTA, Chapter 2: Fire Behaviour

• listen

• take notes

• ask questions
 
IFSTA Essentials of Fire Fighting, 4th Edition
 

• lead lesson
• record on flip chart

• answer questions
• involve learners
• explain the concept that only gases burn

• explain the significance of each process
• explain the difference between supporting combustion and being flammable
• explain the concept of being exothermic and self sustaining (i.e. no external source of ignition required at this point)
 

Combustion

• complete
• incomplete
 
    • explain how we almost never deal with complete combustion
 
Stages of Fire

• ignition
• growth
• fully developed
• decay
 
    • explain the special significance of a fire in decay stages
 
Classification of fire

• "A"
• "B"
• "C"
• "D"
 

    • give examples of each
 
Special fire situations

 

• backdraft
- temperatures o O2 starvation
- smouldering
- smoke colour
- pressure
- amount of flame
- O2 introduction

• flashover
- 4800C - 6500C
- pyrolytic action

- fast heat increase
- room and contents

• rollover
- superheated air

- ignition temperature

• BLEVE
- increased pressure
- flame impingement
- area above liquid level
 

 

 

Read IFSTA, Chapter 2: Fire Behaviour

• listen

• take notes

• ask questions
 
IFSTA Essentials of Fire Fighting, 4th Edition
 

• lead lesson
• record on flip chart

• answer questions
• involve learners
• cover backdraft thoroughly; point out the dangers and how to avoid
• explain the dangers and preventative measures of flashover; outline survival techniques
• define BLEVE
• explain BLEVE theory and how cooling the area above the liquid can help avoid it
 

Methods of extinguishment

• cooling
- reduce temperature
- reduce vapour production

• fuel removal
- shut-off fuel
- remove solids
- least used method

• smothering
- remove O2

• chemical flame inhibition
- special agents
 

Read IFSTA, Chapter 2: Fire Behaviour

• listen

• take notes

• ask questions
 
IFSTA Essentials of Fire Fighting, 4th Edition
 

• lead lesson
• record on flip chart

• answer questions
• involve learners
• remind learners that only gases burn
 

Methods of heat transfer
 

• convection
- liquids
- gases
- heat rises
- direct flame contact

• conduction
- solids

• radiation
- heated waves

• direct flame contact

 

    • explain each of the methods and examples of where they can be found in actual fire situations, i.e. for conduction the example could be a steel beam heating a combustible surface some distance away from the actual fire
 
Spontaneous combustion

• chemical
• biological
 
    • discuss how for a biological reaction the agent(s) must have been formerly living matter
 

 Summary:

As mentioned earlier, it is imperative that firefighters understand how fires burn so that you can understand what is happening when fire reacts in a certain way. Only through this understanding can you learn how to protect yourself and others from the many dangers involved in fire fighting.

This knowledge also allows us to take measures necessary to prevent fires. That, after all, is the ultimate goal of the fire service.

Evaluation:

1) Practical self-check
2) Any testing the trainer wishes to provide

Practical Self-Check

Directions: The firefighter will relate to a supervisor the principles of fire behaviour as they apply to a structure fire.

  Level of Performance
  Yes No N/A
Fire behaviour and spread

• conduction, e.g. metal pipes
• convection, e.g. flashover
• radiation, e.g. exposures

Rollover

• cause
• method to prevent

Flashover

• cause
• method to prevent

Backdraft

• cause
• method to prevent

BLEVE (Boiling Liquid Expanding Vapour Explosion)

• cause
• method to prevent

Method of extinguishment

• cooling, e.g. water
• oxygen removal
• fuel removal
• interruption of chemical chain reaction